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Amide groups can isomerize about the C'N bond between the cis and trans forms, albeit slowly ( seconds at room temperature)

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[DOI] [PubMed] [Google Scholar] 136.Wang SM, Tsai YJ, Jiang MJ, Tseng YZ

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A compound, or a pharmaceutically acceptable salt thereof, as claimed by X 1 is selected from the group consisting of Y, F, D-Tyr, and desY, X 6 is F